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[null,null,null,"Solid-Liquid-Vapor Equilibrium with the Peng-Robinson Equation of State"]
[null,null,null,null,"Version 1.4",null,null,null,"For Educational Use Only!"]
[null,null,null,null,null,"Report errors to R. L. Smith;  Email: smith@scf.che.tohoku.ac.jp"]
[{"$f":"COLUMN()","v":1},{"$f":"COLUMN()","v":2},{"$f":"COLUMN()","v":3},{"$f":"COLUMN()","v":4},{"$f":"COLUMN()","v":5},{"$f":"COLUMN()","v":6},{"$f":"COLUMN()","v":7},{"$f":"COLUMN()","v":8},{"$f":"COLUMN()","v":9},{"$f":"COLUMN()","v":10},{"$f":"COLUMN()","v":11},{"$f":"COLUMN()","v":12},{"$f":"COLUMN()","v":13},{"$f":"COLUMN()","v":14},{"$f":"COLUMN()","v":15},{"$f":"COLUMN()","v":16},{"$f":"COLUMN()","v":17},{"$f":"COLUMN()","v":18},{"$f":"COLUMN()","v":19},{"$f":"COLUMN()","v":20},{"$f":"COLUMN()","v":21},{"$f":"COLUMN()","v":22},{"$f":"COLUMN()","v":23}]
[null,null,null,"Pure component properties",null,null,null,null,null,null,null,null,"Solid Properties",null,null,null,"Binary Interaction"]
[null,null,null,null,null,null,null,null,null,null,null,null,"ln(Psub [Pa] )=A+B/(t[K]+C)",null,null,null," Parameters"]
[null,"No.","Substance Name","Formula","MW","Tc / K","Pc/ Pa","Acentric \nfactor",null,null,"Tmelt [C]","Density [kg/m3]","Solid Molar\nVolume (cm3/mol)","A","B","C","amix term k(i,j)","j = 1",2,null,"bmix term l(i,j)","j=1",2]
[null,1,"Carbon Dioxide","CO2",44.01,304.10000000000002,7380000,0.22500000000000001,"solvent",null,null,null,null,null,null,null,"i = 1",0,0.08,null,"i=1",0,-0.04]
[null,2,"Biphenyl","C12H10",154.21100000000001,801,3380000,0.40400000000000003,"solid solute",null,69.2,{"$f":"1/M9*E9*1000","v":1040.9815039827192},148.13999999999999,30.608000000000001,-9115.9,0,2,{"$f":"S8","v":0.08},0,null,2,{"$f":"W8","v":-0.04},0]
[null,null,null,null,null,null,null,null,null,"Pmelt [MPa]:",{"$f":"EXP(N9+O9/(K9+273.15+P9))/1000000","v":5.3547650942526655E-5}]
[]
[]
[]
[null,null,null,null,"Calculation range",null,{"$f":"COLUMN()-7","v":0},{"$f":"COLUMN()-7","v":1},2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19]
[null,null,null,"Pstart:",0.1,"MPa",null,null,null,"Data Table for Calculations",null,null,null,null,null,null,null,null,null,null,null,null,null,null,"Number of"]
[null,null,null,"Pend:",40,"MPa",null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,"Ideal gas","Enhancement","Iterations"]
[null,null,null,"Pinc:",1,"MPa",null,null,"Solid phase properties",null,null,null,"Vapor phase properties",null,null,null,null,"Liquid phase properties",null,null,null,"Equilibrium ratios, Ki=yi/xi","solubility","Factor","SV +SLV+T",null,"Notes"]
[null,null,null,"Tstart:",69.2,"oC","P [MPa]","T [oC]","fs [Pa]","rho [kg/m3]","y(1) [-]","y(2) [-]","fv(1) [Pa]","fv(2) [Pa]","rho  [kg/m3]","x(1) [-]","x(2) [-]","fL(1) [Pa]","fL(2) [Pa]","rho  [kg/m3]","K(1) [-]","K(2) [-]","y(2)ideal [-]","E [-]","N",null,null,null,null,null,null,"T [C]",64.19]
[null,null,null,null,null,null,0.1,69.19,53.785082159742188,1040.9815039827192,0.99944321333530406,5.5678666469594019E-4,99591.067851502594,53.785082137857003,1.5539516365760682,3.553254084284065E-3,0.99644674591571591,99591.067851502594,53.792720107371437,915.48085082400564,281.27547021076009,5.5877212402782612E-4,5.3506017424526564E-4,1.0406056953899083," 2+ 2+ 1","Number of substances: 2",null,null,null,null,null,"P [MPa]",15.97]
[null,null,null,"Convergence Criteria",null,null,1.1000000000000001,67.207144585432673,48.53316280355714,1040.9815039827192,0.9999346790715482,6.5320928451785971E-5,1056912.5388971176,48.533162805037477,17.826367271306282,4.0092582811813562E-2,0.9599074171881864,1056912.5388971176,48.540071148856349,915.87784976213834,24.94064011203864,6.8049196497645194E-5,4.1652155715066614E-5,1.5682484454978107," 2+ 3+ 3"]
[null,null,null,"Mole fraction, Dy/y:",1.0000000000000001E-5,null,2.1,65.173720137745192,43.566305888969389,1040.9815039827192,0.99995490433423639,4.5095665763580815E-5,1942110.2178653963,43.566305891610639,35.682729182784286,7.8590754323665649E-2,0.92140924567633431,1942110.2178653965,43.572390546575946,916.36761554637485,12.723569240932006,4.8942059106949404E-5,1.8573768285963338E-5,2.4279222756138688," 2+ 3+ 3",null,null,null,null,null,"y1","y2","ysum","F","ln phi","ln (y2)","Psub [Pa]","-(Poynting+ln(Psub/P))"]
[null,null,null,"Mole fraction, Dx/x:",1.0000000000000001E-5,null,3.1,63.086510899902578,38.888760081567021,1040.9815039827192,0.9999586651889194,4.1334811080635612E-5,2753535.9155082339,38.888760086569476,55.520247522272463,0.11930349952914415,0.88069650047085579,2753535.9155082339,38.894074498768475,916.97180825886187,8.3816373294619382,4.6934228827452316E-5,1.0644326228406651E-5,3.8832717255813587," 2+ 3+ 3",null,null,null,null,null,{"$f":"(1-AF22)","v":0.99999998999999995},1E-8,{"$f":"SUM(AE22:AF22)","v":1},{"$f":"AI22+AJ22+AL22","v":-13.442688533045509},{"$f":"LnPhiV_i_Tci_Pci_wi_kijm_lijm_T_P_xyi(2,$F$8:$F$9,$G$8:$G$9,$H$8:$H$9,$R$8:$S$9,$V$8:$W$9,$AG$18,$AG$19*1000000,AE22:AF22)","v":-7.1795893456704851},{"$f":"LN(AF22)","v":-18.420680743952367},{"$f":"EXP($N$9+$O$9/($AG$18+273.15+$P$9))","v":36.057506861800995},{"$f":"-($M$9/1000000*($AG$19*1000000-AK22)/(8.314*(273.15+$AG$18))+LN(AK22/($AG$19*1000000)))","v":12.157581556577345}]
[null,null,null,"Equilibrium function, F1 (SLV calculation):",1.0000000000000001E-5,null,4.0999999999999996,60.944188290814111,34.509796635638658,1040.9815039827192,0.99995625829367263,4.3741706327409274E-5,3489131.1678163107,34.509796645855914,77.914472943170395,0.16250630824303178,0.83749369175696819,3489131.1678163102,34.514395880731065,917.71889049555625,6.1533381017936604,5.2229296480602809E-5,6.7638602219449323E-6,6.4669737238939344," 2+ 4+ 3",null,null,null,null,null,{"$f":"(1-AF23)","v":0.99999000000000005},1.0000000000000001E-5,1,{"$f":"AI23+AJ23+AL23","v":-6.5354469575443765},{"$f":"LnPhiV_i_Tci_Pci_wi_kijm_lijm_T_P_xyi(2,$F$8:$F$9,$G$8:$G$9,$H$8:$H$9,$R$8:$S$9,$V$8:$W$9,$AG$18,$AG$19*1000000,AE23:AF23)","v":-7.1801030491514926},-11.512925464970229,{"$f":"EXP($N$9+$O$9/($AG$18+273.15+$P$9))","v":36.057506861800995},{"$f":"-($M$9/1000000*($AG$19*1000000-AK23)/(8.314*(273.15+$AG$18))+LN(AK23/($AG$19*1000000)))","v":12.157581556577345}]
[null,null,null,"Equilibrium function, F2 (SLVE calculation):",1.0000000000000001E-5,null,5.0999999999999996,58.749644086989349,30.44620863654325,1040.9815039827192,0.99994851213627622,5.1487863723824041E-5,4146318.8247606945,30.446208659528072,103.74330977038731,0.20845948874610493,0.79154051125389513,4146318.824760695,30.450150839310922,918.64237066902524,4.7968481461363091,6.5047667165210639E-5,4.5400001930894263E-6,11.340938663878568," 2+ 4+ 3",null,null,null,null,null,0.99990000000000001,1E-4,1,{"$f":"AI24+AJ24+AL24","v":-4.2374871934821705},-7.1847283780833333,-9.2103403719761818,36.057506861800995,12.157581556577345]
[null,null,null,"Calculation aspects",null,null,6.1,56.515656262769085,26.728843297585861,1040.9815039827192,0.99993286438241802,6.7135617582000242E-5,4721913.9562390437,26.728843355946452,134.43621753317089,0.25731265479933524,0.74268734520066482,4721913.9562390437,26.732192796234646,919.78333837604794,3.886061745242237,9.0395531869283483E-5,3.1511135593988644E-6,21.305362792068863," 2+ 4+ 3",null,null,null,null,null,0.99980000000000002,2.0000000000000001E-4,1,-3.5494737020185472,-7.1898620671796536,-8.5171931914162382,36.057506861800995,12.157581556577345]
[null,null,null,"Newton step in Temperature:",0.01,null,7.1,54.277832574198555,23.416162198759672,1040.9815039827192,0.99990120921531866,9.8790784681294721E-5,5212196.7755777519,23.416162365734301,172.52536076012726,0.30884357956022296,0.6911564204397771,5212196.775577751,23.418996741912139,921.18325933401263,3.2375651475064675,1.4293549442604463E-4,2.241087110903636E-6,44.08163529237423," 2+ 5+ 3",null,null,null,null,null,0.99970000000000003,2.9999999999999997E-4,1,-3.149136407072973,-7.1949898803422458,-8.1117280833080727,36.057506861800995,12.157581556577345]
[null,null,null,"Initial x1:",1E-4,null,8.1,52.12360997207719,20.622430675801599,1040.9815039827192,0.9998278080344104,1.7219196558958906E-4,5613645.4938633377,20.622431009168434,223.0053218927867,0.36176547543590154,0.63823452456409846,5613645.4938633377,20.624858458740455,922.85086519577555,2.7637457853867602,2.6979418844067199E-4,1.6336336010124242E-6,105.40427515868626," 2+ 5+ 3",null,null,null,null,null,0.99960000000000004,4.0000000000000002E-4,1,-2.8665762537151274,-7.2001117994361792,-7.8240460108562919,36.057506861800995,12.157581556577345]
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[null,null,null,null,null,null,10.1,48.955149615746166,17.561380433539032,1040.9815039827192,0.99872735314186034,1.2726468581397072E-3,6159142.3362171724,17.56135917723692,411.99563242798985,0.45233781240631443,0.54766218759368557,6159142.3362171724,17.563526981106616,926.45006086164244,2.2079236485424505,2.3237807666281552E-3,9.9447319729938447E-7,1279.7196159692769," 4+ 6+ 3",null,null,null,null,null,0.99944299999999997,5.5699999999999999E-4,1,-2.5435050399916896,-7.2081412785320431,-7.4929453180369903,36.057506861800995,12.157581556577345]
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[null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,4.0000000000000036E-2,0.96,1,0.14598599841320237,-11.970773563643887,-4.0821994520255166E-2,36.057506861800995,12.157581556577345]
[null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,3.0000000000000027E-2,0.97,1,0.15569179760717056,-11.971430551485465,-3.0459207484708574E-2,36.057506861800995,12.157581556577345]
[null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,2.0000000000000018E-2,0.98,1,0.16548003265158151,-11.971898816608244,-2.0202707317519466E-2,36.057506861800995,12.157581556577345]
[null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,1.0000000000000009E-2,0.99,{"$f":"SUM(AE86:AF86)","v":1},0.17535201190014149,-11.972179208823702,-1.0050335853501451E-2,36.057506861800995,{"$f":"-($M$9/1000000*($AG$19*1000000-AK86)/(8.314*(273.15+$AG$18))+LN(AK86/($AG$19*1000000)))","v":12.157581556577345}]
[null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,{"$f":"(1-AF87)","v":1.0000000000000009E-3},0.999,1,{"$f":"AI87+AJ87+AL87","v":0.18430947814060339},{"$f":"LnPhiV_i_Tci_Pci_wi_kijm_lijm_T_P_xyi(2,$F$8:$F$9,$G$8:$G$9,$H$8:$H$9,$R$8:$S$9,$V$8:$W$9,$AG$18,$AG$19*1000000,AE87:AF87)","v":-11.972271578103157},-1.0005003335835344E-3,{"$f":"EXP($N$9+$O$9/($AG$18+273.15+$P$9))","v":36.057506861800995},12.157581556577345]

{"sheet":"Database","index":1,"n_rows":37,"n_cols":9,"rows_kept":37,"cut":false,"hidden":false,"merged":[]}
[null,"Property database"]
[null,null,null,null,null,null,null,null,"Source:  Properties of Gases and Liquids, 4th Ed. R. C. Reid, J. M. Prausnitz, and B. E. Poling, McGraw-Hill, New York, 1987. AND from Properties of Gases and Liquids, 3rd Ed., R. C. Reid, J. M. Prausnitz, and T. K. Sherwood, McGraw-Hill, New York, 1977."]
["Solvents","MW","Tc [K]","Pc [MPa]","w","Vc [cm3/mol]",null,"Tb [K]","Notes"]
["Carbon Dioxide",44.01,304.10000000000002,7.38,0.22500000000000001,94,"CO2",194.7]
["Ethane",30.07,305.39999999999998,4.88,9.8000000000000004E-2,148,"C2H6",184.5]
["Propane",44.094000000000001,369.8,4.25,0.153,203,"C3H8",231.1]
["Water",18.015000000000001,647.29999999999995,22.12,0.34399999999999997,57.1,"H2O",373.2]
["Toluene",92.141000000000005,591.70000000000005,4.1127799999999999,0.25700000000000001,316,"C7H8",383.8]
["m-Xylene",106.16800000000001,617,3.5455000000000001,0.33100000000000002,376,"C8H10",412.3]
["Ammonia",17.030999999999999,405.6,11.27469,0.25,72.5,"NH3",239.7]
[]
[]
["Common co-solvents"]
["Methanol",32.042000000000002,512.6,8.09,0.55600000000000005,118,"CH4O",337.8]
["Acetone",58.08,508.1,4.7,0.30399999999999999,209,"C3H6O",329.4]
["Dimethyl ether",46.069000000000003,400,5.24,0.192,178,"C2H6O",248.3]
["Ethanol",46.069000000000003,516.20000000000005,6.14,0.63500000000000001,167,"C2H6O",351.5]
["Isopropyl alcohol",60.095999999999997,508.3,4.76,0.66500000000000004,220,"C3H8O",355.4]
[]
["Solutes","MW","Tc [K]","Pc [MPa]","w","Vc [cm3/mol]",null,"Tb [K]"]
["Methane",16.042999999999999,190.6,4.5990200000000003,8.0000000000000002E-3,99,"CH4",111.7]
["Benzene",78.114000000000004,562.20000000000005,4.8899999999999997,0.21199999999999999,259,"C6H6",353.3]
["n-Hexane",86.177999999999997,507.5,3.01,0.29899999999999999,370,"C6H14",341.9]
["Naphthalene",128.17400000000001,748.4,4.05,0.30199999999999999,410,"C10H8",491.1]
["n-Octane",114.232,568.79999999999995,2.4900000000000002,0.39800000000000002,492,"C8H18",398.8]
["n-Hexadecane",224.43199999999999,717,1.42,0.74199999999999999,931.5,"C16H34",560,"Vc estimated with Joback Method"]
["isoprene (1,3-butadiene, 2-methyl)",68.119,484,3.85,0.16400000000000001,276,"C5H8",307.2,"Properties from Reid et al. (1977)"]
["Maleic Anhydride",98.058199999999999,719.4,5.99,0.443,225.5,"C4H2O3",472.8]
["4-methyl-4-cyclohexene-1,2-dicarboxylic anhydride",166.1772,849.1,3.61,0.58799999999999997,450.5,"C9H10O3",598.29999999999995]
["Ethyl Vinyl Ether",72.105720000000005,475.1,4.0199999999999996,0.26500000000000001,258.5,"C4H8O",308.8]
["Biphenyl",154.21100000000001,773,3.38,0.40400000000000003,497,"C12H10",528.23]
["Others","MW","Tc [K]","Pc [MPa]","w","Vc [cm3/mol]",null,"Tb [K]"]
["Hydrogen",2.016,33.200000000000003,1.29664,-0.22,65,"H2",20.399999999999999]
["Hydrogen - Effective Critical Constants",2.016,43.6,2.0499999999999998,0,51.5,"H2",20.399999999999999]
["Nitrogen",28.013000000000002,126.2,3.3935499999999998,0.04,89.5,"N2",77.400000000000006]
["Oxygen",31.998999999999999,154.6,5.04474,2.1000000000000001E-2,73.400000000000006,"O2",90.2]
["Carbon Monoxide",28.01,132.9,3.49485,0.29499999999999998,93.1,"CO",81.7]