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[null,null,null,"Solid-Vapor Equilibrium with the Peng-Robinson Equation of State",null,null,null,null,null,null,null,null,null,null,null,null,null,{"$f":"COLUMN()","v":18},null,null,null,null,null,null,{"$f":"COLUMN()","v":25}]
[null,null,null,null,"Version 1.3",null,null,null,"For Educational Use Only!"]
[null,null,null,null,null,"Report errors to R. L. Smith;  Email: smith@scf.che.tohoku.ac.jp"]
[]
[null,null,null,"Pure component properties",null,null,null,null,null,null,null,null,"Solid Properties",null,null,null,"Binary Interaction"]
[null,null,null,null,null,null,null,null,null,null,null,null,"ln(Psub [Pa] )=A-B/(t[K]+C)",null,null,null," Parameters"]
["No.","Solvent/Co-Solvent Moles used for Mole Ratios- these do not need to sum to 100 and can be set equal to zero except for the solvent.","Substance Name","Formula","MW","Tc / K","Pc/ Pa","Acentric \nfactor","Role","Tmelt [C]","Density [kg/m3]","Solid Molar\nVolume (cm3/mol)","A","B","C",null,"amix term k(i,j)","j=1",2,3,4,5,null,"bmix term l(i,j)","j=1",2,3,4,5]
[1,100,"Carbon Dioxide","CO2",44.01,304.10000000000002,7380000,0.22500000000000001,"solvent",null,null,null,null,null,null,null,"i=1",0,0.10299999999999999,0,0,0,null,"i=1",0,0,0,0,0]
[2,null,"Naphthalene","C10H8",128.19999999999999,748.4,4050000,0.30199999999999999,"solid solute",80.3,{"$f":"1/L9*E9*1000","v":996.88958009331247},128.6,32.896000000000001,9166,0,null,2,{"$f":"S8","v":0.10299999999999999},0,0,0,0,null,2,{"$f":"Z8","v":0},0,0,0,0]
[3,0,"Ethanol","C2H6O",46.069000000000003,516.20000000000005,6140000,0.63500000000000001,"co-solvent",null,null,null,null,null,null,null,3,{"$f":"T8","v":0},{"$f":"T9","v":0},0,0,0,null,3,{"$f":"AA8","v":0},{"$f":"AA9","v":0},0,0,0]
[4,0,"Hydrogen","H2",2.016,33.200000000000003,1296640,-0.22,"co-solvent",null,null,null,null,null,null,null,4,{"$f":"U8","v":0},{"$f":"U9","v":0},{"$f":"U10","v":0},0,0,null,4,{"$f":"AB8","v":0},{"$f":"AB9","v":0},{"$f":"AB10","v":0},0,0]
[5,0,"n-Hexane","C6H12",86.177999999999997,507.5,3010000,0.29899999999999999,"co-solvent",null,null,null,null,null,null,null,5,{"$f":"V8","v":0},{"$f":"V9","v":0},{"$f":"V10","v":0},{"$f":"V11","v":0},0,null,5,{"$f":"AC8","v":0},{"$f":"AC9","v":0},{"$f":"AC10","v":0},{"$f":"AC11","v":0},0,null,5.1000000000000004E-3]
["Total",{"$f":"B8+B10+B11+B12","v":100},null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,null,0.4]
[null,null,null,"Temperature:",40,"oC"]
[null,null,null,"Calculation range",null,null,null,null,null,"Data Table for Calculations",null,null,null,null,null,null,null,null,null,"T [C]",100]
[null,null,null,"Pstart:",0.1,"MPa",null,null,null,null,null,null,null,"Enhancement","Number of",null,null,null,null,"P [MPa]",10]
[null,null,null,"Pend:",20,"MPa",null,"Solid phase properties",null,null,null,"Vapor phase properties",null,"Factor","Iterations","Notes"]
[null,null,null,"Pinc:",0.1,"MPa","P [MPa]","fs [Pa]","rho [kg/m3]","y(2) [-]","fv (2)[Pa]","rho  [kg/m3]","y(2)ideal [-]","E [-]","N",null,null,null,"y1","y2","y3","y4","y5","ysum","F","ln phi","ln (y2)","Psub [Pa]","-(Poynting+ln(Psub/P))"]
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[null,null,null,"Convergence Criteria:",null,null,0.2,37.923057511918657,996.88958009331247,2.0306841863628196E-4,37.923057511918657,3.4143562927001287,1.8775166773192655E-4,1.0815798394197211,2,null,null,null,{"$f":"$B$8/$B$13*(1-T20)","v":0.99999000000000005},1.0000000000000001E-5,{"$f":"$B$10/$B$13*(1-T20)","v":0},{"$f":"$B$11/$B$13*(1-T20)","v":0},{"$f":"$B$12/$B$13*(1-T20)","v":0},{"$f":"SUM(S20:W20)","v":1},{"$f":"Z20+AA20+AC20","v":-6.3751292245367299},{"$f":"LnPhiV_i_Tci_Pci_wi_kijm_lijm_T_P_xyi(2,$F$8:$F$12,$G$8:$G$12,$H$8:$H$12,$R$8:$V$12,$Y$8:$AC$12,$U$15,$U$16*1000000,S20:W20)","v":-2.2337980558897952},-11.512925464970229,4155.348928032251,{"$f":"-($L$9/1000000*($U$16*1000000-AB20)/(8.314*(273.15+$U$15))+LN(AB20/($U$16*1000000)))","v":7.371594296323293}]
[null,null,null,"Mole fraction, Dy/y:",1E-3,null,0.3,38.11083992098736,996.88958009331247,1.4082631707502841E-4,38.110839920987367,5.1455765769681676,1.2516777848795103E-4,1.1251003954550869,2,null,null,null,0.99990000000000001,1E-4,{"$f":"$B$10/$B$13*(1-T21)","v":0},0,0,1,{"$f":"Z21+AA21+AC21","v":-4.0737819906391834},-2.2350359149862951,-9.2103403719761818,4155.348928032251,7.371594296323293]
[null,null,null,"Equilibrium function, F1:",0.01,null,0.4,38.299552166294738,996.88958009331247,1.0988940379345232E-4,38.299552166294738,6.8936862447342238,9.3875833865963277E-5,1.1705824520328987,2,null,null,null,0.99980000000000002,2.0000000000000001E-4,0,0,0,1,-3.3820109435146151,-2.2364120484216699,-8.5171931914162382,4155.348928032251,7.371594296323293]
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[null,null,null,null,null,null,17.5,89.128935447612719,996.88958009331247,1.4182630978150331E-2,89.128935447612719,824.72763608546745,2.1457333455077321E-6,6609.6894135717412,3]
[null,null,null,null,null,null,17.600000000000001,89.570272389150773,996.88958009331247,1.4267579686728905E-2,89.570272389150773,826.23045170333478,2.1335416787718928E-6,6687.2748860203174,3]
[null,null,null,null,null,null,17.7,90.013794684917372,996.88958009331247,1.4351991134536753E-2,90.013794684917372,827.71859057868846,2.1214877709822209E-6,6765.059563785263,3]
[null,null,null,null,null,null,17.8,90.459513156062187,996.88958009331247,1.4435873042202963E-2,90.459513156062187,829.19234734879819,2.1095693003587253E-6,6843.0428143546605,3]
[null,null,null,null,null,null,17.899999999999999,90.907438677317657,996.88958009331247,1.4519232933963011E-2,90.907438677317657,830.65200758701417,2.0977839970047658E-6,6921.2239938400226,3]
[null,null,null,null,null,null,18,91.357582177264291,996.88958009331247,1.4602078144872601E-2,91.357582177264291,832.09784817779769,2.0861296414658504E-6,6999.6024478192212,3]
[null,null,null,null,null,null,18.100000000000001,91.809954638597276,996.88958009331247,1.4684415827679816E-2,91.809954638597276,833.53013767233176,2.0746040633362052E-6,7078.1775121299843,3]
[null,null,null,null,null,null,18.2,92.26456709839448,996.88958009331247,1.476625295937453E-2,92.264567098394465,834.94913662591864,2.0632051399112809E-6,7156.9485136167741,3]
[null,null,null,null,null,null,18.3,92.721430648385748,996.88958009331247,1.4847596347432599E-2,92.721430648385763,836.35509791826985,2.0519307948844433E-6,7235.914770833564,3]
[null,null,null,null,null,null,18.399999999999999,93.180556435223451,996.88958009331247,1.4928452635774704E-2,93.180556435223451,837.74826705774763,2.040778997086158E-6,7315.0755947065691,3]
[null,null,null,null,null,null,18.5,93.641955660754491,996.88958009331247,1.5008828310453318E-2,93.641955660754491,839.12888247049818,2.0297477592640709E-6,7394.430289158242,3]
[null,null,null,null,null,null,18.600000000000001,94.105639582293648,996.88958009331247,1.5088729705084243E-2,94.105639582293634,840.49717577538786,2.0188351369024361E-6,7473.97815169562,3]
[null,null,null,null,null,null,18.7,94.571619512898152,996.88958009331247,1.5168163006035703E-2,94.571619512898152,841.85337204557038,2.0080392270794282E-6,7553.7184739647146,3]
[null,null,null,null,null,null,18.8,95.039906821643754,996.88958009331247,1.5247134257389845E-2,95.039906821643768,843.19769005747401,1.9973581673609209E-6,7633.6505422738737,3]
[null,null,null,null,null,null,18.899999999999999,95.510512933902092,996.88958009331247,1.5325649365686774E-2,95.510512933902106,844.53034252791042,1.9867901347293815E-6,7713.7736380869756,3]
[null,null,null,null,null,null,19,95.983449331619482,996.88958009331247,1.5403714104464025E-2,95.983449331619482,845.85153634001551,1.9763333445465953E-6,7794.0870384888949,3]
[null,null,null,null,null,null,19.100000000000001,96.458727553596987,996.88958009331247,1.5481334118602502E-2,96.458727553597001,847.16147275862329,1.9659860495489693E-6,7874.5900166250849,3]
[null,null,null,null,null,null,19.2,96.936359195772013,996.88958009331247,1.5558514928487662E-2,96.936359195772013,848.46034763568048,1.9557465388742348E-6,7955.2818421161273,3]
[null,null,null,null,null,null,19.3,97.416355911501242,996.88958009331247,1.563526193399651E-2,97.416355911501242,849.74835160625059,1.9456131371184099E-6,8036.161781449232,3]
[null,null,null,null,null,null,19.399999999999999,97.898729411844869,996.88958009331247,1.5711580418319718E-2,97.898729411844883,851.0256702756235,1.9355842034219233E-6,8117.2290983482826,3]
[null,null,null,null,null,null,19.5,98.383491465852359,996.88958009331247,1.5787475551625157E-2,98.383491465852359,852.29248439801268,1.9256581305838619E-6,8198.4830541225801,3]
[null,null,null,null,null,null,19.600000000000001,98.870653900849604,996.88958009331247,1.5862952394573984E-2,98.870653900849618,853.54897004729219,1.9158333442033321E-6,8279.9229079971628,3]
[null,null,null,null,null,null,19.7,99.360228602727631,996.88958009331247,1.593801590169323E-2,99.360228602727616,854.79529878020389,1.90610830184697E-6,8361.5479174240536,3]
[null,null,null,null,null,null,19.8,99.852227516232247,996.88958009331247,1.60126709246146E-2,99.852227516232261,856.0316377924305,1.8964814922416824E-6,8443.3573383768035,3]
[null,null,null,null,null,null,19.899999999999999,100.34666264525585,996.88958009331247,1.6086922215185005E-2,100.34666264525585,857.25815006790208,1.8869514344917241E-6,8525.3504256288579,3]
[null,null,null,null,null,null,20,100.84354605313003,996.88958009331247,1.6160774428454112E-2,100.84354605313003,858.47499452169745,1.8775166773192656E-6,8607.5264330160862,3]
[null,null,null,null,null,null,20.100000000000001,101.34288986292005,996.88958009331247,1.6234232125547105E-2,101.34288986292005,859.68232613686382,1.8681757983276273E-6,8689.8846136856228,3,"Upper pressure bound reached."]

{"sheet":"Database","index":1,"n_rows":37,"n_cols":9,"rows_kept":37,"cut":false,"hidden":false,"merged":[]}
[null,"Property database"]
[null,null,null,null,null,null,null,null,"Source:  Properties of Gases and Liquids, 4th Ed. R. C. Reid, J. M. Prausnitz, and B. E. Poling, McGraw-Hill, New York, 1987. AND from Properties of Gases and Liquids, 3rd Ed., R. C. Reid, J. M. Prausnitz, and T. K. Sherwood, McGraw-Hill, New York, 1977."]
["Solvents","MW","Tc [K]","Pc [MPa]","w","Vc [cm3/mol]",null,"Tb [K]","Notes"]
["Carbon Dioxide",44.01,304.10000000000002,7.38,0.22500000000000001,94,"CO2",194.7]
["Ethane",30.07,305.39999999999998,4.88,9.8000000000000004E-2,148,"C2H6",184.5]
["Propane",44.094000000000001,369.8,4.25,0.153,203,"C3H8",231.1]
["Water",18.015000000000001,647.29999999999995,22.12,0.34399999999999997,57.1,"H2O",373.2]
["Toluene",92.141000000000005,591.70000000000005,4.1127799999999999,0.25700000000000001,316,"C7H8",383.8]
["m-Xylene",106.16800000000001,617,3.5455000000000001,0.33100000000000002,376,"C8H10",412.3]
["Ammonia",17.030999999999999,405.6,11.27469,0.25,72.5,"NH3",239.7]
[]
[]
["Common co-solvents"]
["Methanol",32.042000000000002,512.6,8.09,0.55600000000000005,118,"CH4O",337.8]
["Acetone",58.08,508.1,4.7,0.30399999999999999,209,"C3H6O",329.4]
["Dimethyl ether",46.069000000000003,400,5.24,0.192,178,"C2H6O",248.3]
["Ethanol",46.069000000000003,516.20000000000005,6.14,0.63500000000000001,167,"C2H6O",351.5]
["Isopropyl alcohol",60.095999999999997,508.3,4.76,0.66500000000000004,220,"C3H8O",355.4]
[]
["Solutes","MW","Tc [K]","Pc [MPa]","w","Vc [cm3/mol]",null,"Tb [K]"]
["Methane",16.042999999999999,190.6,4.5990200000000003,8.0000000000000002E-3,99,"CH4",111.7]
["Benzene",78.114000000000004,562.20000000000005,4.8899999999999997,0.21199999999999999,259,"C6H6",353.3]
["n-Hexane",86.177999999999997,507.5,3.01,0.29899999999999999,370,"C6H14",341.9]
["Naphthalene",128.17400000000001,748.4,4.05,0.30199999999999999,410,"C10H8",491.1]
["n-Octane",114.232,568.79999999999995,2.4900000000000002,0.39800000000000002,492,"C8H18",398.8]
["n-Hexadecane",224.43199999999999,717,1.42,0.74199999999999999,931.5,"C16H34",560,"Vc estimated with Joback Method"]
["isoprene (1,3-butadiene, 2-methyl)",68.119,484,3.85,0.16400000000000001,276,"C5H8",307.2,"Properties from Reid et al. (1977)"]
["Maleic Anhydride",98.058199999999999,719.4,5.99,0.443,225.5,"C4H2O3",472.8]
["4-methyl-4-cyclohexene-1,2-dicarboxylic anhydride",166.1772,849.1,3.61,0.58799999999999997,450.5,"C9H10O3",598.29999999999995]
["Ethyl Vinyl Ether",72.105720000000005,475.1,4.0199999999999996,0.26500000000000001,258.5,"C4H8O",308.8]
["Biphenyl",154.21100000000001,773,3.38,0.40400000000000003,497,"C12H10",528.23]
["Others","MW","Tc [K]","Pc [MPa]","w","Vc [cm3/mol]",null,"Tb [K]"]
["Hydrogen",2.016,33.200000000000003,1.29664,-0.22,65,"H2",20.399999999999999]
["Hydrogen - Effective Critical Constants",2.016,43.6,2.0499999999999998,0,51.5,"H2",20.399999999999999]
["Nitrogen",28.013000000000002,126.2,3.3935499999999998,0.04,89.5,"N2",77.400000000000006]
["Oxygen",31.998999999999999,154.6,5.04474,2.1000000000000001E-2,73.400000000000006,"O2",90.2]
["Carbon Monoxide",28.01,132.9,3.49485,0.29499999999999998,93.1,"CO",81.7]